The structure of the adduct of benzonitrile oxide to indene, and the synthesis of 1- and 2-benzoylindane

oa South African Journal of Chemistry - The structure of the adduct of benzonitrile oxide to indene, and the synthesis of 1- and 2-benzoylindane

Author F.V.K.** Perold, G.W.* & Von Reiche¹
Affiliations : 1 *Research Laboratory, Scientific and Research Department, S.A. Iron and Steel Industrial Corporation, Ltd., Pretoria & **Research Laboratory, Scientific and Research Department, S.A. Iron and Steel Industrial Corporation, Ltd., Pretoria.
Source : South African Journal of Chemistry, Volume 10, Issue 1, Jan 1927, p. 5 - 10
Keyword(s) : Refluxing constant-boiling hydriodic acid cleaves the 2-isoxazolinc obtained by addition of benzonitrile oxide to indene, to 2-benzoyl-indane. The addition therefore follows the Markownikoff rule and leads to 3-phenyl-4, 5-(indano-2', 1') -2-isoxazoline. The nature of the by-products of the cleavage reaction is discussed. The synthesis of the hitherto unknown 1- and 2-benzoylindanes by the reaction of diphenylcadmium with the corresponding acid chlorides is described.
Accreditation : SciELO SA
The Arts and Humanities Citation Index of the ISI

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1927-01-01

2018-04-26