oa South African Journal of Chemistry - Hexamethylphosphoramide and octamethylpyrophosphoramide complexes of tetravalent metal chlorides
|Article Title||Hexamethylphosphoramide and octamethylpyrophosphoramide complexes of tetravalent metal chlorides|
|© Publisher:||South African Chemical Institute (SACI)|
|Journal||South African Journal of Chemistry|
|Affiliations||1 *Department of Chemistry, University College Western Cape, Kasselsvlei & **Department of Chemistry, University College Western Cape, Kasselsvlei.|
|Publication Date||Oct 1966|
|Pages||73 - 84|
|Keyword(s)||, Absorption spectra, Conductivity in non-aqueous solvents, Hexamethylphosphoramide (HMPA), Magnetic properties, MCl4,2HMPA (M=Sn, T1, Zr, and Hf), MCl4,OMPA (M=Sn, T1, Zr and Hf), Octamethylphosphoramide (OMPA) and X-ray diffraction|
The hexamethylphosphoramide (HMPA) complexes MCl4,2HMPA (M=Sn, T1, Zr, and Hf) and octamethylphosphoramide (OMPA) complexes MCl4,OMPA (M=Sn, T1, Zr and Hf), ThCl4,2OMPA and UCl4, 1.5 OMPA have been prepared and their conductivity in non-aqueous solvents, absorption spectra and magnetic properties (in the case of the U(IV) compound) investigated. The unit cell dimensions of SnCl4,2HMPA and UCl4,2HMPA have been determined by X-ray diffraction.
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