oa South African Journal of Chemistry - The rotational fine structure of the v2 parallel infrared band of monodeuteromethane
|Article Title||The rotational fine structure of the v2 parallel infrared band of monodeuteromethane|
|© Publisher:||South African Chemical Institute (SACI)|
|Journal||South African Journal of Chemistry|
|Affiliations||1 Departments of Applied Mathematics and of Chemistry, University of Cape Town, Rondebosch, Cape Town.|
|Publication Date||Oct 1966|
|Pages||93 - 97|
|Keyword(s)||Coriolis coupling, Determination of bond properties, Methane, Monodeuteromethane, Rotational line structure, Spherical symmetry, Triply degenerate vibrations, v2 parallel infrared band and Vibration-rotation data|
The rotational line structure of the ?2 parallel infrared band of monodeuteromethane has been measured and analysed The ground state constants are in good agreement with those of the parallel band ?3 and the perpendicular band ?1. The moment of inertia of the excited state about the figure axis of the molecule was found to be smaller than that of the ground state.
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