oa South African Journal of Chemistry - The Synthesis of QADMAA and its Application to the Solid Phase Extraction and Spectrophotometric Determination of Cobalt
|Article Title||The Synthesis of QADMAA and its Application to the Solid Phase Extraction and Spectrophotometric Determination of Cobalt|
|© Publisher:||South African Chemical Institute (SACI)|
|Journal||South African Journal of Chemistry|
|Author||Yunhuai Zhang, Zhong Li, Shengtao Zhang, Guangyu Yang and Jiayuang Yin|
|Publication Date||Jan 2004|
|Pages||28 - 32|
|Keyword(s)||2-(2-Quinolylazo)-5-dimethylaminoaniline, Cobalt, Solid phase extraction and Spectrophotometry|
In this paper, the synthesis of a new chromogenic reagent, 2-(2-quinolylazo)-5-dimethylaminoaniline (QADMAA), is reported. A sensitive, selective and rapid method for the determination of cobalt based on the rapid reaction of cobalt(II) with QADMAA and the solid phase extraction of the Co(II)-QADMAAchelate withC<sub>18</sub> membrane disks was developed. In the presence of a pH=5.5 buffer solution and a cetyl trimethylammonium bromide (CTMAB) medium, QADMAA reacts with cobalt to form a violet complex with a molar ratio of 1:2 (cobalt to QADMAA). This chelate was enriched by solid phase extraction with C<sub>18</sub> membrane disks and an enrichment factor of 50 was obtained. The molar absorptivity of the chelate is 1.32x10<sup>5</sup> L mol<sup>-1</sup> cm<sup>-1</sup> at 616 nm in the measured solution. Beer's law is obeyed in the range of 0.01~0.6 <span style='font-family:Graeca'>m<o:p></o:p></span>g mL<sup>-1</sup>. The relative standard deviation for eleven replicate sample at the 0.01 <span style='font-family:Graeca'>m<o:p></o:p></span>g mL<sup>-1</sup> level is 1.35%. The detection limit reached 0.02 <span style='font-family:Graeca'>m<o:p></o:p></span>g L<sup>-1</sup> in the original samples. This method was applied with good results to the determination of cobalt in environmental samples.
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