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oa South African Journal of Chemistry - Study on Colour Reaction of Vanadium(V) with 2-(2-Quinolylazo)-5-Diethylaminophenol and Its Application

 

Abstract

A sensitive, selective and rapid method has been developed for the determination of vanadium based on the rapid reaction of vanadium(V) with 2-(2-quinolylazo)-5-diethylaminophenol (QADEAP). The QADEAP reacts with V(V) in the presence of citric acid-sodium hydroxide buffer solution (pH =3.5) and cetyl trimethylammonium bromide (CTMAB) medium to form a violet chelate of a molar ratio 1:2 (V(V) to QADEAP). The molar absorptivity of the chelate is 1.23 x 10&lt;sup&gt;5&lt;/sup&gt; L mol&lt;sup&gt;-1&lt;/sup&gt; cm&lt;sup&gt;-1&lt;/sup&gt; at 590 nm in the measured solution. Beer's law is obeyed in the range of 0.01~0.6 <SPAN lang=AF style="FONT-FAMILY: Symbol; mso-ascii-font-family: 'Times New Roman'; mso-hansi-font-family: 'Times New Roman'; mso-char-type: symbol; mso-symbol-font-family: Symbol"><SPAN style="mso-char-type: symbol; mso-symbol-font: Symbol">m</SPAN></SPAN>g mL<sup>-1</sup>. This method was applied to the determination of vanadium(v) with good results.

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/content/chem/57/1/EJC24349
2004-01-01
2016-12-08
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