oa South African Journal of Chemistry - Tetrameric DABCO()-Bromine : an Efficient and Versatile Reagent for Bromination of Various Organic Compounds
|Article Title||Tetrameric DABCO()-Bromine : an Efficient and Versatile Reagent for Bromination of Various Organic Compounds|
|© Publisher:||South African Chemical Institute (SACI)|
|Journal||South African Journal of Chemistry|
|Author||Majid M. Heravi, Fatemeh Derikvand and Mitra Ghassemzadeh|
|Publication Date||Jan 2006|
|Pages||125 - 128|
|Keyword(s)||(alpha)-bromination, 1, 2-dibromo compounds, Bromination, Bromohydrin, Solid supports, TDB and Tetrameric DABCO-Bromine|
Tetrameric DABCO-bromine is a powerful brominating agent but shows reasonable selectivity with certain substrates. The selective bromination for activated aromatic compounds and alkenes is reported. Synthesis of α-bromo ketones and nitriles has also been achieved by using this reagent and the results are also reported. All products reported were obtained in good to excellent yields.
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