oa South African Journal of Chemistry - Synthesis of Furanylalkyl Hex- and Pentenopyranosid-4-uloses
|Article Title||Synthesis of Furanylalkyl Hex- and Pentenopyranosid-4-uloses|
|© Publisher:||South African Chemical Institute (SACI)|
|Journal||South African Journal of Chemistry|
|Author||Soro Yaya, Siaka Sorho, Louis Cottier and Gerard Descotes|
|Publication Date||Jan 2006|
|Pages||117 - 121|
|Keyword(s)||Hydroxymethylfurfural (HMF), Oxidation, Pyranone and Silylation|
A few novel furanylalkyl hex- and pentenopyranones have been synthesized from the corresponding hexenopyranosides or hydroxymethylfurfural. In the hexose series, the reactions proceeded through monosilylation of the primary alcohol followed by oxidation of secondary alcohols. The pentenopyranones have been obtained by glycosidation of hydroxymethylfurfural oxidation product.
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