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oa South African Journal of Chemistry - Solvent-free Oxidation of Alcohols and Mild Catalytic Deprotection of Silyl Ethers with Poly(-dibromo--ethyl-benzene-1,3-disulphonamide) and -tetrabromobenzene-1,3-disulphonamide

 

Abstract

Poly(-dibromo--ethyl-benzene-1,3-disulphonamide) (PBBS) and -tetrabromobenzene-1,3-disulphonamide (TBBDA) can be used for solvent-free oxidation of primary and secondary alcohols to the corresponding carbonyl compounds without over-oxidation, and efficient catalytic deprotection of various silyl ethers to hydroxyl groups in aprotic organic solvents under ambient conditions.

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/content/chem/60/1/EJC24416
2007-01-01
2016-12-09
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