oa South African Journal of Chemistry - Preparation, structure characterization and thermal decomposition process of the dysprosium(III) m-Methylbenzoate 1,10-phenanthroline complex : research article
|Article Title||Preparation, structure characterization and thermal decomposition process of the dysprosium(III) m-Methylbenzoate 1,10-phenanthroline complex : research article|
|© Publisher:||South African Chemical Institute (SACI)|
|Journal||South African Journal of Chemistry|
|Author||Su-Ling Xu, Jian-Jun Zhang, Ning Ren, Hai-Yan Zhang, Rui-Fen Wang and Shu-Ping Wang|
|Publication Date||Jan 2008|
|Pages||1 - 4|
|Keyword(s)||1,10-phenanthroline, Crystal structure, Dysprosium complex, m-Methylbenzoic acid, and Thermal analysis|
A dinuclear complex [Dy(m-MBA)3phen]2∙H2O was prepared by the reaction of DyCl3∙6H2O, m-methylbenzoic acid and 1,10-phenanthroline in a 1:3:1 molar ratio, where m-MBA = m-methylbenzoate and phen = 1,10-phenanthroline. The complex was structurally characterized by single crystal X-ray diffraction, elemental analysis, UV and IR spectroscopy, molar conductance and TG-DTG techniques. It crystallizes in the monoclinic space group Cc with a =15.962(16), b = 18.505(18), c = 22.547(2) Å; α = 90°, ß = 97.9820(10) °, y = 90°; z = 4. The unit cell contains a dinuclear molecule of the title compound. Each Dy(III) ion is eight-coordinated to one 1,10-phenanthroline molecule, one bidentate carboxylate group and four bridging carboxylate groups. The carboxylate groups are bonded to the dysprosium ions in two modes : chelating bidentate and bridging bidentate. The thermal decomposition process of [Dy(m-MBA)3phen]2∙H2O has been followed by thermal analysis.
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