oa South African Journal of Chemistry - Coordination of the bidentate ligands 2,2'-dipyridylamine,1-phenyl-1,3-butadione and '-(propan-2-ylidene)benzohydrazide to rhenium(III) : research article

Volume 63, Issue 1
  • ISSN : 0379-4350



The reaction of -[ReCl(MeCN)(PPh)] with 1-phenyl-1,3-butadione (Hbat), 2,2'-dipyridylamine (dpa), and 1-(2-hydroxyphenyl) ethanone benzoylhydrazone (Hhaep) under nitrogen led to the respective complexes -[ReIIICl(bat)(PPh)], -[ReIIICl(dpa)(PPh)] and -[ReVOCl(meb)(PPh)] (meb = '-(propan-2-ylidene)benzohydrazide). All the complexes were characterized by 1H NMR and infrared spectroscopy, and X-ray crystallography.

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