oa South African Journal of Chemistry - Synthesis and spectroscopic, thermal and crystal structure studies of hydrazinium Hydrogensuccinate : research article
|Article Title||Synthesis and spectroscopic, thermal and crystal structure studies of hydrazinium Hydrogensuccinate : research article|
|© Publisher:||South African Chemical Institute (SACI)|
|Journal||South African Journal of Chemistry|
|Affiliations||1 Bharathiar University, India, 2 Bharathiar University, India, 3 Bharathiar University, India, 4 Sungkyunkwan University, South Korea and 5 University of Missouri, USA|
|Publication Date||Jan 2014|
|Pages||85 - 90|
|Keyword(s)||Crystal structure, Hydrazine, Hydrazinium hydrogensuccinate, Succinic acid and Thermal studies|
The mono-hydrazinium salt of succinic acid (hydrazinium hydrogensuccinate salt) was prepared by reacting hydrazine hydrate and succinic acid. Its spectral, thermal and structural properties have been determined. The salt, N2H5+.C4H5O4-, is a molecular salt containing discrete hydrazinium cations and hydrogen succinate anions. The crystal packing consists of infinite chains of anions and cations that are alternatively linked through O-H∙∙∙N and bifurcated N-H∙∙∙O bonds and this chain is connected to adjacent antiparallel chains by N-H∙∙∙O hydrogen bonding. The adjacent chains are cross linked by N-H∙∙∙O bonds from the donor N2H5+ ions, thus forming a three-dimensional network. The salt undergoes melting followed by decomposition to give gaseous products.
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