n Suid-Afrikaanse Tydskrif vir Natuurwetenskap en Tegnologie - Die effek van substituente in fosfien-ligande : referaatopsomming

Volume 30, Issue 1
  • ISSN : 0254-3486
  • E-ISSN: 2222-4173


The study illustrates the use of the P-atom to evaluate steric and electronic effects in P-containing organic compounds. The work involves the synthesis of substituted triarylphosphines and their corresponding Rh Vaska complexes. High resolution X-ray crystallography, molecular modelling, 31P NMR spectroscopy and IR will be used to quantify substituent effects.

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