n Suid-Afrikaanse Tydskrif vir Natuurwetenskap en Tegnologie - Elektroniese eienskappe van die Mn(asas)-kompleks : 'n sikliese voltammetrie- en berekeningschemiestudie : referaatopsomming

Volume 32, Issue 1
  • ISSN : 0254-3486
  • E-ISSN: 2222-4173



Tris(acetylacetonato) Manganese(III) is a catalyst in alkyd paint. In this study, the electronic properties of Mn(acac) are determined by means of electrochemistry and computational chemistry. The optimised geometrical and electronic structure of Mn(acac) is calculated by means of computational chemistry, and electrochemistry is applied to measure the following reactions:

MnIII(acac) - e- ⇆ MnIV(acac)

MnIII(acac) + e- ⇆ MnII(acac)

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