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n Suid-Afrikaanse Tydskrif vir Natuurwetenskap en Tegnologie - 'n Elektrochemiese en berekeningschemiestudie van tenoïelbevattende Rh(I) β-diketonatokomplekse : referaatopsomming

Volume 33, Issue 1
  • ISSN : 0254-3486
  • E-ISSN: 2222-4173
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Abstract


The electrochemical properties of [Rh((CHS)COCHCO(R))(CO)(PPh)] (with R = CHS, CH, CF) were determined through cyclic voltammetry and the results were compared with Hammett constants and group electro-negativities. We obtained good correlations which enable the synthesis of rhodium complexes with specific characteristics through modelling with computational chemistry.

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/content/aknat/33/1/EJC156079
2014-01-01
2019-10-23

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